Preface IX 1. Introductory and Historical 1 1. Introduction 1 2. Production management 1 3. Primitive methods of leather manufacture 5 4. Use of leather by the ancients 7 5. Methods of production of leather 16 6. Vegetable tannages 20 7. Combination tanning 25 8. Oils & fats in the leather industry 31 9. Conclusion 33 References 33 MCQs 33 Answers 34 2. Introductory Sketch of Leather Manufacture 35 1. Introduction 35 2. The object of tanning 35 3. Leather and Suede 38 4. Removal of hair by liming 42 5. Unhairing by putrefaction 43 6. Deliming 51 7. Conclusion 52 References 52 MCQs 52 Answers 53 3. Putrefaction and Fermentation 54 1. Introduction 54 2. Fermentation 54 3. What is Putrefaction? 55 4. Classification of organised ferments 57 5. The alcoholic fermentation 64 6. Fermentation in bating and puering 66 7. Fermentation in tanning liquors 72 8. Conclusion 75 References 75 MCQs 76 Answers 76 4. The Origin and Curing of Hides and Skins 77 1. Introduction 77 2. Curing 78 3. Leather and Skin 79 4. Archaeological Leather 83 5. Chemical Deterioration 88 6. Conservation and care 89 7. Marking of hides 91 8. Fellmongering of sheep-skins 93 9. The use of salt 93 10. Drying of hides and skins 101 11. Conclusion 107 References 108 MCQs 108 Answers 108 5. Structure and Growth of Skin 109 1. Introduction 109 2. The Skin 109 3. Structure of calf- skin 115 4. Sources of Leather 117 5. Chemical Alterations Through Tanning 119 6. Leather Manufacture 120 7. The hair-sheath 124 8. Conclusion 126 References 126 MCQs 127 Answers 127 6. The Physical Chemistry of the Hide-Fibre 128 1. Introduction 128 2. Fibre Briefing: Leather 129 3. Raw Hide and Curing Process 131 4. The essentials of the tanning process 133 5. Preparation 139 6. Effect of salt 144 7. The pickling process 146 8. Conclusion 149 References 150 MCQs 150 Answers 150 7. Water as used in the Tannery 151 1. Introduction 151 2. Leather’s Water Footprint 151 3. Dyestuffs for Leather, Classses and Structures 154 4. Aspects of the Affinity of Dyestuffs to Leather 156 5. The Influence of Auxiliary Agents on Dye Affinity 159 6. Further Influences 162 7. Effect of hardness on plumbing 165 8. Washing of fresh hides 170 9. Danger of putrefaction 172 10. Soaking and softening of dry and dry-salted hides 174 11. Conclusion 179 References 179 MCQs 180 Answers 180 8. Alum Tannage or Tawing 181 1. Introduction 181 2. Nature of leather 182 3. Production processes 184 4. From other animals 187 5. Natural leather grain 191 6. Leather Grades and Leather Qualities 192 7. Types of Leather Grades – For Raw Hides 194 8. Types of Leather Cuts 195 9. Types of Leather from Different Animal Hides 197 10. Exotic Animal Leathers 198 11. Types of Leather Used for Furs 199 12. Finished Leathers 200 13. Conclusion 204 References 204 MCQs 205 Answers 205 9. Iron and Chrome Tannages 206 1. Introduction 206 2. Tanning Operation 207 3. Chrome tannages 212 4. Knapp's method of chrome tannage 219 5. Types of Tannage 222 6. Development of chrome tanning 225 7. Future of Chrome Tanning 227 8. Organic Tanning Options 233 9. Alternative Technologies 236 10. Conclusion 238 References 239 MCQs 239 Answers 240 10. Dyes and Dyeing 241 1. Introduction 241 2. Development of High Fastness Dyes 242 3. Leather Colour - Leather Colour - Leather Dye 243 4. Dyestuffs and Dyeing of Leather 249 5. Conclusion 259 References 260 MCQs 261 Answers 261 Index 263 |